AA 5180 then AA 6032 at Charlotte
White Plains → Charlotte → Greenville
Timetable, Charlotte time
15:43AA 5180 from White Plains at the gate
15:40AA 6032 to Greenville leaves the gate
23 h 57 apart on the timetable, overnight
AA 6032 leaves 23 h 57 after AA 5180 arrives on the timetable: more than half a day, so not a connection we count.