AA 5332 then AA 3268 at Charlotte
Washington → Charlotte → Punta Cana
Timetable, Charlotte time
11:08AA 5332 from Washington at the gate
07:10AA 3268 to Punta Cana leaves the gate
20 h 02 apart on the timetable, overnight
AA 3268 leaves 20 h 02 after AA 5332 arrives on the timetable: more than half a day, so not a connection we count.