AA 5374 then AA 5543 at Charlotte
Pensacola → Charlotte → Pittsburgh
Timetable, Charlotte time
15:35AA 5374 from Pensacola at the gate
08:35AA 5543 to Pittsburgh leaves the gate
17 h apart on the timetable, overnight
AA 5543 leaves 17 h after AA 5374 arrives on the timetable: more than half a day, so not a connection we count.