AA 5385 then AA 5902 at Charlotte
Lexington → Charlotte → Greenville
Timetable, Charlotte time
10:40AA 5385 from Lexington at the gate
22:45AA 5902 to Greenville leaves the gate
12 h 05 apart on the timetable
AA 5902 leaves 12 h 05 after AA 5385 arrives on the timetable: more than half a day, so not a connection we count.