AA 5425 then AA 5030 at Charlotte
Washington National → Charlotte → Toronto
Timetable, Charlotte time
14:20AA 5425 from Washington National at the gate
13:00AA 5030 to Toronto leaves the gate
22 h 40 apart on the timetable, overnight
AA 5030 leaves 22 h 40 after AA 5425 arrives on the timetable: more than half a day, so not a connection we count.