AA 5467 then AA 3268 at Charlotte
Pittsburgh → Charlotte → Punta Cana
Timetable, Charlotte time
10:15AA 5467 from Pittsburgh at the gate
07:10AA 3268 to Punta Cana leaves the gate
20 h 55 apart on the timetable, overnight
AA 3268 leaves 20 h 55 after AA 5467 arrives on the timetable: more than half a day, so not a connection we count.