AA 5564 then AA 5968 at Charlotte
Harrisburg → Charlotte → Charlottesville
Timetable, Charlotte time
18:46AA 5564 from Harrisburg at the gate
15:27AA 5968 to Charlottesville leaves the gate
20 h 41 apart on the timetable, overnight
AA 5968 leaves 20 h 41 after AA 5564 arrives on the timetable: more than half a day, so not a connection we count.