AA 5567 then AA 5543 at Charlotte
Asheville → Charlotte → Pittsburgh
Timetable, Charlotte time
17:20AA 5567 from Asheville at the gate
08:35AA 5543 to Pittsburgh leaves the gate
15 h 15 apart on the timetable, overnight
AA 5543 leaves 15 h 15 after AA 5567 arrives on the timetable: more than half a day, so not a connection we count.