AA 5594 then AA 2059 at Charlotte
Little Rock → Charlotte → San Diego
Timetable, Charlotte time
13:38AA 5594 from Little Rock at the gate
10:42AA 2059 to San Diego leaves the gate
21 h 04 apart on the timetable, overnight
AA 2059 leaves 21 h 04 after AA 5594 arrives on the timetable: more than half a day, so not a connection we count.