AA 5594 then AA 5180 at Charlotte
Little Rock → Charlotte → White Plains
Timetable, Charlotte time
13:38AA 5594 from Little Rock at the gate
11:05AA 5180 to White Plains leaves the gate
21 h 27 apart on the timetable, overnight
AA 5180 leaves 21 h 27 after AA 5594 arrives on the timetable: more than half a day, so not a connection we count.