AA 5594 then AA 5374 at Charlotte
Little Rock → Charlotte → Pensacola
Timetable, Charlotte time
13:38AA 5594 from Little Rock at the gate
11:10AA 5374 to Pensacola leaves the gate
21 h 32 apart on the timetable, overnight
AA 5374 leaves 21 h 32 after AA 5594 arrives on the timetable: more than half a day, so not a connection we count.