AA 5658 then AA 5222 at Charlotte
Pittsburgh → Charlotte → Washington
Timetable, Charlotte time
17:25AA 5658 from Pittsburgh at the gate
17:15AA 5222 to Washington leaves the gate
23 h 50 apart on the timetable, overnight
AA 5222 leaves 23 h 50 after AA 5658 arrives on the timetable: more than half a day, so not a connection we count.