AA 567 then AA 5220 at Charlotte
Philadelphia → Charlotte → Washington
Timetable, Charlotte time
10:30AA 567 from Philadelphia at the gate
09:45AA 5220 to Washington leaves the gate
23 h 15 apart on the timetable, overnight
AA 5220 leaves 23 h 15 after AA 567 arrives on the timetable: more than half a day, so not a connection we count.