AA 5785 then AA 5543 at Charlotte
Asheville → Charlotte → Pittsburgh
Timetable, Charlotte time
11:30AA 5785 from Asheville at the gate
08:35AA 5543 to Pittsburgh leaves the gate
21 h 05 apart on the timetable, overnight
AA 5543 leaves 21 h 05 after AA 5785 arrives on the timetable: more than half a day, so not a connection we count.