AA 5793 then AA 5543 at Charlotte
Charlottesville → Charlotte → Pittsburgh
Timetable, Charlotte time
13:43AA 5793 from Charlottesville at the gate
08:35AA 5543 to Pittsburgh leaves the gate
18 h 52 apart on the timetable, overnight
AA 5543 leaves 18 h 52 after AA 5793 arrives on the timetable: more than half a day, so not a connection we count.