AA 5803 then AA 6052 at Charlotte
Charlottesville → Charlotte → Tallahassee
Timetable, Charlotte time
15:30AA 5803 from Charlottesville at the gate
14:20AA 6052 to Tallahassee leaves the gate
22 h 50 apart on the timetable, overnight
AA 6052 leaves 22 h 50 after AA 5803 arrives on the timetable: more than half a day, so not a connection we count.