AA 5822 then AA 506 at Charlotte
Tri-Cities → Charlotte → Chicago O'Hare
Timetable, Charlotte time
13:12AA 5822 from Tri-Cities at the gate
13:09AA 506 to Chicago O'Hare leaves the gate
23 h 57 apart on the timetable, overnight
AA 506 leaves 23 h 57 after AA 5822 arrives on the timetable: more than half a day, so not a connection we count.