AA 5822 then AA 5585 at Charlotte
Tri-Cities → Charlotte → Roanoke
Timetable, Charlotte time
12:25AA 5822 from Tri-Cities at the gate
11:30AA 5585 to Roanoke leaves the gate
23 h 05 apart on the timetable, overnight
AA 5585 leaves 23 h 05 after AA 5822 arrives on the timetable: more than half a day, so not a connection we count.