AA 5825 then AA 5814 at Charlotte
Knoxville → Charlotte → Huntington
Timetable, Charlotte time
17:36AA 5825 from Knoxville at the gate
17:20AA 5814 to Huntington leaves the gate
23 h 44 apart on the timetable, overnight
AA 5814 leaves 23 h 44 after AA 5825 arrives on the timetable: more than half a day, so not a connection we count.