AA 5826 then AA 5966 at Charlotte
Knoxville → Charlotte → Charlottesville
Timetable, Charlotte time
11:31AA 5826 from Knoxville at the gate
11:26AA 5966 to Charlottesville leaves the gate
23 h 55 apart on the timetable, overnight
AA 5966 leaves 23 h 55 after AA 5826 arrives on the timetable: more than half a day, so not a connection we count.