AA 5831 then AA 6012 at Charlotte
Tri-Cities → Charlotte → Asheville
Timetable, Charlotte time
16:41AA 5831 from Tri-Cities at the gate
15:55AA 6012 to Asheville leaves the gate
23 h 14 apart on the timetable, overnight
AA 6012 leaves 23 h 14 after AA 5831 arrives on the timetable: more than half a day, so not a connection we count.