AA 5852 then AA 3268 at Charlotte
Charlottesville → Charlotte → Punta Cana
Timetable, Charlotte time
12:23AA 5852 from Charlottesville at the gate
07:10AA 3268 to Punta Cana leaves the gate
18 h 47 apart on the timetable, overnight
AA 3268 leaves 18 h 47 after AA 5852 arrives on the timetable: more than half a day, so not a connection we count.