AA 5852 then AA 5543 at Charlotte
Charlottesville → Charlotte → Pittsburgh
Timetable, Charlotte time
11:39AA 5852 from Charlottesville at the gate
08:35AA 5543 to Pittsburgh leaves the gate
20 h 56 apart on the timetable, overnight
AA 5543 leaves 20 h 56 after AA 5852 arrives on the timetable: more than half a day, so not a connection we count.