AA 588 then AA 5968 at Charlotte
Phoenix → Charlotte → Charlottesville
Timetable, Charlotte time
15:45AA 588 from Phoenix at the gate
15:27AA 5968 to Charlottesville leaves the gate
23 h 42 apart on the timetable, overnight
AA 5968 leaves 23 h 42 after AA 588 arrives on the timetable: more than half a day, so not a connection we count.