AA 5969 then AA 5040 at Charlotte
Charlottesville → Charlotte → Washington National
Timetable, Charlotte time
10:26AA 5969 from Charlottesville at the gate
10:20AA 5040 to Washington National leaves the gate
23 h 54 apart on the timetable, overnight
AA 5040 leaves 23 h 54 after AA 5969 arrives on the timetable: more than half a day, so not a connection we count.