AA 5977 then WN 544 at Charlotte
Roanoke → Charlotte → Baltimore
Timetable, Charlotte time
06:30AA 5977 from Roanoke at the gate
20:05WN 544 to Baltimore leaves the gate
13 h 35 apart on the timetable
WN 544 leaves 13 h 35 after AA 5977 arrives on the timetable: more than half a day, so not a connection we count.