AA 6039 then AA 5131 at Charlotte
Roanoke → Charlotte → New Orleans
Timetable, Charlotte time
20:50AA 6039 from Roanoke at the gate
19:30AA 5131 to New Orleans leaves the gate
22 h 40 apart on the timetable, overnight
AA 5131 leaves 22 h 40 after AA 6039 arrives on the timetable: more than half a day, so not a connection we count.