AA 6039 then AA 6066 at Charlotte
Roanoke → Charlotte → Tallahassee
Timetable, Charlotte time
20:50AA 6039 from Roanoke at the gate
19:55AA 6066 to Tallahassee leaves the gate
23 h 05 apart on the timetable, overnight
AA 6066 leaves 23 h 05 after AA 6039 arrives on the timetable: more than half a day, so not a connection we count.