AA 662 then AA 5258 at Charlotte
Puerto Plata → Charlotte → Lexington
Timetable, Charlotte time
19:15AA 662 from Puerto Plata at the gate
17:16AA 5258 to Lexington leaves the gate
22 h 01 apart on the timetable, overnight
AA 5258 leaves 22 h 01 after AA 662 arrives on the timetable: more than half a day, so not a connection we count.