AA 662 then AA 5968 at Charlotte
Puerto Plata → Charlotte → Charlottesville
Timetable, Charlotte time
19:15AA 662 from Puerto Plata at the gate
15:27AA 5968 to Charlottesville leaves the gate
20 h 12 apart on the timetable, overnight
AA 5968 leaves 20 h 12 after AA 662 arrives on the timetable: more than half a day, so not a connection we count.