AA 662 then AA 6032 at Charlotte
Puerto Plata → Charlotte → Greenville
Timetable, Charlotte time
19:15AA 662 from Puerto Plata at the gate
15:40AA 6032 to Greenville leaves the gate
20 h 25 apart on the timetable, overnight
AA 6032 leaves 20 h 25 after AA 662 arrives on the timetable: more than half a day, so not a connection we count.