AA 662 then AA 6067 at Charlotte
Puerto Plata → Charlotte → Roanoke
Timetable, Charlotte time
19:15AA 662 from Puerto Plata at the gate
16:30AA 6067 to Roanoke leaves the gate
21 h 15 apart on the timetable, overnight
AA 6067 leaves 21 h 15 after AA 662 arrives on the timetable: more than half a day, so not a connection we count.