AA 878 then AA 6066 at Charlotte
Orlando → Charlotte → Tallahassee
Timetable, Charlotte time
20:01AA 878 from Orlando at the gate
19:55AA 6066 to Tallahassee leaves the gate
23 h 54 apart on the timetable, overnight
AA 6066 leaves 23 h 54 after AA 878 arrives on the timetable: more than half a day, so not a connection we count.