AC 8749 then AA 5935 at Charlotte
Toronto → Charlotte → Charlottesville
Timetable, Charlotte time
22:00AC 8749 from Toronto at the gate
21:45AA 5935 to Charlottesville leaves the gate
23 h 45 apart on the timetable, overnight
AA 5935 leaves 23 h 45 after AC 8749 arrives on the timetable: more than half a day, so not a connection we count.