DY 3303 then FR 606 at Copenhagen
Berlin → Copenhagen → Madrid
Timetable, Copenhagen time
13:40DY 3303 from Berlin at the gate
06:10FR 606 to Madrid leaves the gate
16 h 30 apart on the timetable, overnight
FR 606 leaves 16 h 30 after DY 3303 arrives on the timetable: more than half a day, so not a connection we count.