EI 3197 then EI 594 at Dublin
Liverpool → Dublin → Madrid
Timetable, Dublin time
21:45EI 3197 from Liverpool at the gate
16:15EI 594 to Madrid leaves the gate
18 h 30 apart on the timetable, overnight
EI 594 leaves 18 h 30 after EI 3197 arrives on the timetable: more than half a day, so not a connection we count.