FR 421 then EI 594 at Dublin
Amsterdam → Dublin → Madrid
Timetable, Dublin time
20:00FR 421 from Amsterdam at the gate
16:15EI 594 to Madrid leaves the gate
20 h 15 apart on the timetable, overnight
EI 594 leaves 20 h 15 after FR 421 arrives on the timetable: more than half a day, so not a connection we count.