FR 5307 then EI 594 at Dublin
Killarney → Dublin → Madrid
Timetable, Dublin time
18:45FR 5307 from Killarney at the gate
17:50EI 594 to Madrid leaves the gate
23 h 05 apart on the timetable, overnight
EI 594 leaves 23 h 05 after FR 5307 arrives on the timetable: more than half a day, so not a connection we count.