AZ 1462 then FR 9601 at Fiumicino
Venezia → Rome → Madrid
Timetable, Rome time
16:25AZ 1462 from Venezia at the gate
10:40FR 9601 to Madrid leaves the gate
18 h 15 apart on the timetable, overnight
FR 9601 leaves 18 h 15 after AZ 1462 arrives on the timetable: more than half a day, so not a connection we count.