AZ 159 then FR 9601 at Fiumicino
Brussels → Rome → Madrid
Timetable, Rome time
13:40AZ 159 from Brussels at the gate
10:40FR 9601 to Madrid leaves the gate
21 h apart on the timetable, overnight
FR 9601 leaves 21 h after AZ 159 arrives on the timetable: more than half a day, so not a connection we count.