AZ 165 then FR 6926 at Fiumicino
Brussels → Rome → Barcelona
Timetable, Rome time
21:00AZ 165 from Brussels at the gate
18:30FR 6926 to Barcelona leaves the gate
21 h 30 apart on the timetable, overnight
FR 6926 leaves 21 h 30 after AZ 165 arrives on the timetable: more than half a day, so not a connection we count.