AZ 1710 then FR 9601 at Fiumicino
Catania → Rome → Madrid
Timetable, Rome time
11:45AZ 1710 from Catania at the gate
10:40FR 9601 to Madrid leaves the gate
22 h 55 apart on the timetable, overnight
FR 9601 leaves 22 h 55 after AZ 1710 arrives on the timetable: more than half a day, so not a connection we count.