AZ 1722 then FR 1003 at Fiumicino
Catania → Rome → Valencia
Timetable, Rome time
07:25AZ 1722 from Catania at the gate
19:55FR 1003 to Valencia leaves the gate
12 h 30 apart on the timetable
FR 1003 leaves 12 h 30 after AZ 1722 arrives on the timetable: more than half a day, so not a connection we count.