AZ 1724 then FR 9601 at Fiumicino
Catania → Rome → Madrid
Timetable, Rome time
12:55AZ 1724 from Catania at the gate
10:40FR 9601 to Madrid leaves the gate
21 h 45 apart on the timetable, overnight
FR 9601 leaves 21 h 45 after AZ 1724 arrives on the timetable: more than half a day, so not a connection we count.