AZ 1726 then FR 9601 at Fiumicino
Catania → Rome → Madrid
Timetable, Rome time
16:50AZ 1726 from Catania at the gate
10:40FR 9601 to Madrid leaves the gate
17 h 50 apart on the timetable, overnight
FR 9601 leaves 17 h 50 after AZ 1726 arrives on the timetable: more than half a day, so not a connection we count.