AZ 203 then FR 9601 at Fiumicino
London Heathrow → Rome → Madrid
Timetable, Rome time
14:10AZ 203 from London Heathrow at the gate
06:00FR 9601 to Madrid leaves the gate
15 h 50 apart on the timetable, overnight
FR 9601 leaves 15 h 50 after AZ 203 arrives on the timetable: more than half a day, so not a connection we count.