AZ 207 then FR 4861 at Fiumicino
London Heathrow → Rome → Catania
Timetable, Rome time
20:10AZ 207 from London Heathrow at the gate
19:00FR 4861 to Catania leaves the gate
22 h 50 apart on the timetable, overnight
FR 4861 leaves 22 h 50 after AZ 207 arrives on the timetable: more than half a day, so not a connection we count.