AZ 59 then FR 4906 at Fiumicino
Madrid → Rome → Palermo
Timetable, Rome time
08:15AZ 59 from Madrid at the gate
05:45FR 4906 to Palermo leaves the gate
21 h 30 apart on the timetable, overnight
FR 4906 leaves 21 h 30 after AZ 59 arrives on the timetable: more than half a day, so not a connection we count.