AZ 59 then FR 6007 at Fiumicino
Madrid → Rome → Porto
Timetable, Rome time
08:15AZ 59 from Madrid at the gate
21:25FR 6007 to Porto leaves the gate
13 h 10 apart on the timetable
FR 6007 leaves 13 h 10 after AZ 59 arrives on the timetable: more than half a day, so not a connection we count.