AZ 59 then FR 6342 at Fiumicino
Madrid → Rome → Barcelona
Timetable, Rome time
08:15AZ 59 from Madrid at the gate
21:05FR 6342 to Barcelona leaves the gate
12 h 50 apart on the timetable
FR 6342 leaves 12 h 50 after AZ 59 arrives on the timetable: more than half a day, so not a connection we count.